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Material Safety Data Sheet

Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act and shall not be used for any other purpose. Black Swan Manufacturing Co. urges the customers receiving this Material Safety Data Sheet to study it carefully to become aware of the hazards, if any, of the product involved. In the interest of safety, you should notify your employees, agents, and contractors of the information on the sheet.

SECTION I - GENERAL INFORMATION
Black Swan Manufacturing Co.
4540 W. Thomas Street
Chicago, IL 60651-3318
Telephone No: 1-773-227-3700
Fax No: 1-773-227-3705

For chemical emergencies during
transportation only call

INFOTRAC
1-800-535-5053
24 hours per day - 7 days a week
Date Prepared

01/01/08

 		Trade Name

ROOF-PROOF

SECTION II - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
HAZARDOUS COMPONENTS CAS#  APPROX% ACGIH-TLV   OSHA-PEL
PETROLEUM ASPHALT 8052-42-4 35% 5.0mg/m3 (FUME) (FUME)
PETROLEUM SOLVENTS 64742-48-9 20% 100 PPM
CELLULOSIC FIBER 9004-24-6 5% 10 mg/m3 *
INORGANIC FILLERS 50% 10 mg/m3 *

* AS RESPIRABLE DUST.

*Title III Section 313 Supplier Notification: this product contains toxic chemicals subject to the reporting requirements of Section 313 of the Emergency planning and community Right-to-Know Act of 1966 and of 40CFR372. This information must be included in all MSDS's that are copied and distributed for this material.

SHIPPING INFORMATION

NOT HAZARDOUS FOR SHIPPING PURPOSES.

 

 

 

SPECIAL HAZARD DESIGNATIONS

HMIS   HAZARD RATING
HEALTH 2 2 0 - MINIMAL
FLAMMABILITY 2 2 1- SLIGHT
REACTIVITY 0 0 2- MODERATE
PROTECTIVE 3- SERIOUS
EQUIPMENT B 4- SEVERE

SECTION III - PHYSICAL DATA
APPEARANCE

BLACK PASTE

 		ODOR

SLIGHT PETROLEUM HYDROCARBON SOLVENT

ODOR.

 		BOILING POINT

300-390° F
SPECIFIC GRAVITY (H2O=1)

GREATER THAN 1.00

 		VAPOR PRESSURE (mm Hg.)

6mm Hg 106° F

 		VOLATILE BY VOLUME (%)

LESS THAN 25
VAPOR DENSITY (AIR=1)

3.9 (AIR = 1.0)

 

 EVAPORATION RATE (BUAC=1)

ETHYLETHER = 1

 		SOLUBILITY IN WATER

INSOLUBLE

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT ( METHOD USED) FLAMMABLE LIMITS LEL UEL
103° F VIA TCC (PERCENT BY VOLUME) 0.9% 6.0%
FIRE EXTINGUISHING MEDIA

EXTINGUISH WITH DRY CHEMICAL & CO2 OR UNIVERSAL TYPE FOAM AND WATER FOG ARE EFFECTIVE BUT MAY CAUSE FROTHING. DO NOT USE WATER. PETROLEUM BASED COMPOUNDS CAN FLOAT ON WATER.
SPECIAL FIRE FIGHTING PROCEDURES

SAME AS ABOVE.
UNUSUAL FIRE AND EXPLOSION HAZARD

DO NOT USE LIQUID WATER. THIS MAY CAUSE FIRE TO SPREAD.

SECTION V - HEALTH HAZARD DATA
PRIMARY ROUTES OR ENTRY __X___Inhalation __X___Skin contact __X___Eye contact __X___Ingestion

 

EFFECT OF OVEREXPOSURE

REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVER-EXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THIS PRODUCT MAY BE HARMFUL OR FATAL.

REPEATED SKIN CONTACT HAS BEEN SHOWN TO PRODUCE SKIN TUMORS ON LABORATORY ANIMALS.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

PERSONS WITH PRE-EXISTING CENTRAL NERVOUS SYSTEM DISEASE, SKIN DISORDERS, OR CHRONIC RESPIRATORY DISEASE SHOULD AVOID EXPOSURE TO THIS PRODUCT.
EMERGENCY AND FIRST AID PROCEDURES

SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE.

EYES: FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION.

INGESTION: DO NOT INDUCE VOMITING. KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.

INHALATION: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM, QUIET, AND GET MEDICAL ATTENTION.

SECTION VI - REACTIVITY
STABILITY UNSTABLE   CONDITIONS TO AVOID

AVOID CONTACT WITH STRONG OXIDANTS SUCH AS
  STABLE X LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM

HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
INCOMPATIBILITY (MATERIALS TO AVOID)

CONTACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS

MAY FORM TOXIC MATERIALS - CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS.
HAZARDOUS
POLYMERIZATION		 MAY OCCUR  

CONDITIONS TO AVOID

KEEP AWAY FROM SOURCES OF FIRE.
WILL NOT OCCUR X  

SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABORBENT, OR OTHER ABSORBENT MATERIAL AND TRANSFER TO HOOD.

LARGE SPILL: ELIMINATE ALL IGNITION SOURCES ( FLARES, FLAMES, INCLUDING PILOT LIGHTS, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE. DIKE AREA OF SPILL TO PREVENT SPREADING. PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS.
WASTE DISPOSAL METHOD

SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT TIME FOR VAPORS TO COMPLETELY CLEAR HOOD DUCT WORK. DESTROY REMAINING MATERIAL BY BURNING IN AN IRON PAN.

LARGE SPILL: DESTROY BY LIQUID INCINERATION. MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE DEPOSITED IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.

SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)

USE SUPPLIED AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED.
VENTILATION

USE ONLY WITH VENTILATION SUFFICIENT TO PREVENT EXCEEDING RECOMMENDED EXPOSURE LIMIT OR BUILDUP OF EXPLOSIVE CONCENTRATIONS OF VAPOR IN AIR. USE EXPLOSION-PROOF EQUIPMENT. NO SMOKING OR OPEN LIGHTS.
PROTECTIVE GLOVES

CHEMICAL RESISTANT GLOVES

 		EYE PROTECTION

USE SPLASH GOGGLES OR FACE SHIELD
OTHER PROTECTIVE EQUIPMENT AND HYGIENIC PRACTICES

USE CHEMICAL RESISTANT APRON OR OTHER IMPERVIOUS CLOTHING NEEDED, TO AVOID CONTAMINATING REGULAR CLOTHING WHICH COULD RESULT IN PROLONGED OR REPEATED SKIN CONTACT.

SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING

CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE (VAPOR).
OTHER PRECAUTIONS

LIQUID, AND/OR SOLID. ALL HAZARD PRECAUTIONS GIVEN IN THIS DATA SHEET MUST BE OBSERVED.
This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.